DOI: 10.21276/ajptr
Sat, 18 Aug 2018

Synthesis, Characterization and Catalytic Applications of Water Soluble Ni (II) and Mn (II) Metal Complexes

Haroon Rashid Boked1, G.M.Mir2, Ghulam Mohammad Jan1, Fayaz Ahmad Bhat1, ImtiyazRasool Parrey2*

1 Department of Chemistry, Govt. Degree College Boys Anantnag Jammu & Kashmir (India)

2.Department of Chemistry, Govt. Degree College for WomensAnantnag Jammu & Kashmir (India)


ABSTRACT

Ni (II) and Mn (II) metal complexes of Schiff base derived from ethylenediamine, succinic acid and formaldehyde. The newly synthesized Schiff base complexes were characterized by elemental analysis, Melting point, conductivity, IR and UV-VIS spectral methods. The complexes have been tested using for the catalytic oxidation of benzylacohol using ecofriendly molecular oxygen as catalyst. The results show that Nickel complex shows highest yield oxidation product as compared to Manganese at 35°C temperature, 90mg catalyst amount and 25 min. time.

Keywords: Schiff base complex synthesis, characterization, Catalytic activity.


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